Synthesis and reactivity of new aminophenolate complexes of nickel.
نویسندگان
چکیده
New well-defined, paramagnetic nickel complexes have been prepared and characterized by X-ray crystallography. The complexes were found to be active for the cross-coupling of alkyl electrophiles (especially ethyl 2-bromobutyrate) with alkyl Grignard reagents. The ligand architecture in these new complexes could potentially be rendered chiral, opening up future possibilities for performing asymmetric cross-coupling reactions.
منابع مشابه
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عنوان ژورنال:
- Molecules
دوره 19 9 شماره
صفحات -
تاریخ انتشار 2014